Determination of the rate of tetraethylammonium ion transfer across the water/1,2-DCE interface with steady-state voltammetry at a nano-ITIES. Theory and experiment.
In: Journal of Electroanalytical Chemistry, Jg. 784 (2017), S. 1-5
academicJournal
Zugriff:
The rate of TEA + ion transfer across the water/1,2-dichloroethane interface has been measured using steady-state voltammetry at a capillary with an orifice of nano-sized dimension. It is found that the average rate constant for TEA + transfer from water to oil and from oil to water is 0.64 cm s − 1 . The results are repeatable using the same capillary. This value is similar to that measured previously using electrochemical impedance spectroscopy and fluctuation analysis at the micro-interface. [ABSTRACT FROM AUTHOR]
| Titel: |
Determination of the rate of tetraethylammonium ion transfer across the water/1,2-DCE interface with steady-state voltammetry at a nano-ITIES. Theory and experiment.
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| Autor/in / Beteiligte Person: | Silver, B.R. ; Holub, K. ; Mareček, V. |
| Zeitschrift: | Journal of Electroanalytical Chemistry, Jg. 784 (2017), S. 1-5 |
| Veröffentlichung: | 2017 |
| Medientyp: | academicJournal |
| ISSN: | 1572-6657 (print) |
| DOI: | 10.1016/j.jelechem.2016.11.022 |
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