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Chemistry

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  1. Self-Association of Phosphorylase Kinase under Molecular Crowding Conditions

    Self-association of phosphorylase kinase (PhK) has been studied using analytical ultracentrifugation and dynamic light scattering under the...
    Natalia A. Chebotareva, Alexey V. Meremyanin, ... Boris I. Kurganov in Analytical Ultracentrifugation VIII
    Conference paper

  2. Adsorption of Poly(vinyl formamide-co-vinyl amine) (PVFA-co-PVAm) onto Metal Surfaces

    The formation of stable metal/polymer joints is an enormous challenge in material sciences. Good adhesion requires an interphase which is able to...
    Stefan Spange, Susan Wolf, Frank Simon in Characterization of Polymer Surfaces and Thin Films
    Conference paper

  3. High-resolution Grazing Incidence Small Angle X-ray Scattering: Investigation of Micrometer Sized Structured Polymer Films

    While bulk samples are routinely probed by small angle X-ray scattering (SAXS) and ultra-small angle X-ray scattering (USAXS), the grazing...
    P. Müller-Buschbaum in Characterization of Polymer Surfaces and Thin Films
    Conference paper

  4. Ab initio and Constrained Modeling of Phosphorylase

    The joint use of small-angle X-ray scattering (SAXS) and hydrodynamic data permits biologically useful reconstructions of protein structures to be...
    Helmut Durchschlag, Peter Zipper, Angelika Krebs in Analytical Ultracentrifugation VIII
    Conference paper

  5. Polyferrocenylsilane Block Copolymers: Nanotubes and Nanowires through Self-Assembly

    Polyferrocenyldimethylsilane (PFS) diblock copolymers with polyisoprene (PFS-PI) or with polydimethylsiloxane (PFS-PDMS) self-assemble in simple...
    Gérald Guérin, Jose Raez, ... Mitchell A. Winnik in Characterization of Polymer Surfaces and Thin Films
    Conference paper

  6. Carbene Complexes of Heme Proteins and Iron Porphyrin Models

    The possible formation of carbene complexes of cytochromes P450 enzymes in various metabolisms of xenobiotics is first described. In view of these...
    Gérard Simonneaux, Paul Le Maux in Bioorganometallic Chemistry
    Chapter

  7. Ferrocene–Peptide Bioconjugates

    This chapter sketches an outline of ferrocene–peptide bioconjugates. A variety of ferrocene–peptide bioconjugates have been designed to induce...
    Toshiyuki Moriuchi, Toshikazu Hirao in Bioorganometallic Chemistry
    Chapter

  8. Sequentially Palladium-Catalyzed Processes

    Sequentially palladium-catalyzed reactions consist of combinations of identical, related, or significantly different palladium-catalyzed processes...
    Thomas J. J. Müller in Metal Catalyzed Cascade Reactions
    Chapter

  9. Catalytic Nickel–Iron–Sulfur Clusters: From Minerals to Enzymes

    The geochemical theory of the origin of life proposes that primordial, pre-biotic reactions were carried out in a metal-sulfide-rich environment...
    Anne Volbeda, Juan C. Fontecilla-Camps in Bioorganometallic Chemistry
    Chapter

  10. Immobilization of Nucleic Acids Using Biotin-Strept(avidin) Systems

    There are several advantages for using biotin-streptavidin/avidin (strept(avi-din)) systems to immobilize nucleic acids and other molecules. These...
    Cassandra L. Smith, Jaqueline S. Milea, Giang H. Nguyen in Immobilisation of DNA on Chips II
    Chapter

  11. Altitudinal Surface-Mounted Molecular Rotors

    After a general description of some potential applications of artificial altitudinal surface-mounted molecular rotors, the synthesis, surface...
    Thomas F. Magnera, Josef Michl in Molecular Machines
    Chapter

  12. Tin-Free Radical Reactions Mediated by Organoboron Compounds

    The development of tin-free methods to run radical reactions is crucial for their applications in industrial processes as well as in drug...
    Vincent Darmency, Philippe Renaud in Radicals in Synthesis I
    Chapter

  13. Nanostructured Devices Based on Block Copolymer Assemblies for Drug Delivery: Designing Structures for Enhanced Drug Function

    Block copolymers spontaneously assemble into nanoscaled polymeric micelles, which have significant potential as drug carriers. Following much work...
    Nobuhiro Nishiyama, Kazunori Kataoka in Polymer Therapeutics II
    Chapter

  14. Molecular Dynamics Modeling of the Crystal-Melt Interfaces and the Growth of Chain Folded Lamellae

    The molecular mechanism of polymer crystallization is one of the most difficult problems and has defied innumerable efforts to understand the...
    Takashi Yamamoto in Interphases and Mesophases in Polymer Crystallization III
    Chapter

  15. Enzymatic Polymerization to Polysaccharides

    Polysaccharides are formed by repeated glycosylations between a sugar donor and a sugar acceptor. This chapter reviews the in vitro synthesis of...
    Shiro Kobayashi, Masashi Ohmae in Enzyme-Catalyzed Synthesis of Polymers
    Chapter

  16. Polymer Therapeutics for Cancer: Current Status and Future Challenges

    Drug delivery systems for cancer therapeutics have revolutionized medicine. Delivery systems have improved the efficacy and reduced the toxicity of...
    Ronit Satchi-Fainaro, Ruth Duncan, Carmen M. Barnes in Polymer Therapeutics II
    Chapter

  17. Surface-Grafted Polymer Gradients: Formation, Characterization, and Applications

    This review presents to-date progress in the formation of surface-tethered polymer assemblies with gradually varying physico-chemical properties....
    Rajendra R. Bhat, Michael R. Tomlinson, ... Jan Genzer in Surface-Initiated Polymerization II
    Chapter

  18. Topological Mechanism of Polymer Nucleation and Growth – The Role of Chain Sliding Diffusion and Entanglement

    Direct evidence of nucleation during the induction period of nucleation from the melt is obtained for the first time by means of small angle X-ray...
    Masamichi Hikosaka, Kaori Watanabe, ... Shinichi Yamazaki in Interphases and Mesophases in Polymer Crystallization III
    Chapter

  19. Synthesis of Phenol Polymers Using Peroxidases

    This chapter deals with the peroxidase-catalyzed polymerization of phenol and its derivatives. Such a polymerization needs an oxidation reagent,...
    Matthias Reihmann, Helmut Ritter in Enzyme-Catalyzed Synthesis of Polymers
    Chapter

  20. Surface Rearrangement of Diblock Copolymer Brushes—Stimuli Responsive Films

    This article reviews results from our group of the synthesis and characterization of diblock copolymer brushes. Results from the literature are...
    William J. Brittain, Stephen G. Boyes, ... Mark D. Foster in Surface-Initiated Polymerization II
    Chapter